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• W2979076409 abstract "A radical-mediated monofluoroalkylative alkynylation of alkenes is disclosed for the first time. The reaction demonstrates a remarkably broad substrate scope in which both activated and unactivated alkenes are suitable starting materials. The concurrent addition of an alkynyl and a monofluoroalkyl group onto an alkene proceeds through a docking-migration sequence, affording a vast array of valuable fluoroalkyl-substituted alkynes. Many complex natural products and drug derivatives are readily functionalized, demonstrating that this method can be used for late-stage alkynylation." @default.
• W2979076409 created "2019-10-10" @default.
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• W2979076409 date "2019-12-02" @default.
• W2979076409 modified "2023-10-13" @default.
• W2979076409 title "Radical Monofluoroalkylative Alkynylation of Olefins by a Docking–Migration Strategy" @default.
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• W2979076409 doi "https://doi.org/10.1002/anie.201910514" @default.
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