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- W2979355600 abstract "Chemo- and regioselectivity are often difficult to control during olefin hydrosilylation catalyzed by d- and f-block metal complexes. The cationic hydride of calcium [CaH]+ stabilized by an NNNN macrocycle was found to catalyze the regioselective hydrosilylation of aliphatic olefins to give anti-Markovnikov products, while aryl-substituted olefins were hydrosilyated with Markovnikov regioselectivity. Ethylene was efficiently hydrosilylated by primary and secondary hydrosilanes to give di- and monoethylated silanes. Aliphatic hydrosilanes were preferred over other commonly employed hydrosilanes: Arylsilanes such as PhSiH3 underwent scrambling reactions promoted by the nucleophilic hydride, while alkoxy- and siloxy-substituted hydrosilanes gave isolable alkoxy and siloxy calcium derivatives." @default.
- W2979355600 created "2019-10-18" @default.
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- W2979355600 date "2019-11-19" @default.
- W2979355600 modified "2023-10-17" @default.
- W2979355600 title "Regioselective Hydrosilylation of Olefins Catalyzed by a Molecular Calcium Hydride Cation" @default.
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- W2979355600 doi "https://doi.org/10.1002/anie.201909585" @default.
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