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- W2979569884 abstract "We report on the synthesis of highly oriented and nanostructured metal–organic framework (MOF) films featuring extreme surface wetting properties. The Ni- and Co- derivatives of the metal–catecholate series (M-CAT-1) were synthesized as highly crystalline bulk materials and thin films. Oriented pillar-like nanostructured M-CAT-1 films exhibiting pronounced needle-like morphology on gold substrates were established by incorporating a crystallization promoter into the film synthesis. These nanostructured M-CAT-1 MOF films feature extreme wetting phenomena, specifically superhydrophilic and underwater superoleophobic properties with water and underwater oil-contact angles of 0° and up to 174°, respectively. The self-cleaning capability of the nanostructured, needle-like M-CAT-1 films was illustrated by measuring time-dependent oil droplet rolling-off a tilted surface. The deposition of the nanostructured Ni-CAT-1 film on a large glass substrate allowed for the realization of an efficient, transparent, antifog coating, enabling a clear view even at extreme temperature gaps up to ≈120 °C. This work illustrates the strong link between MOF film morphology and surface properties based on these framework materials." @default.
- W2979569884 created "2019-10-18" @default.
- W2979569884 creator A5008264987 @default.
- W2979569884 creator A5049974783 @default.
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- W2979569884 date "2019-10-09" @default.
- W2979569884 modified "2023-09-25" @default.
- W2979569884 title "Nanostructured and oriented metal–organic framework films enabling extreme surface wetting properties" @default.
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- W2979569884 doi "https://doi.org/10.3762/bjnano.10.196" @default.
- W2979569884 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/6808203" @default.
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