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- W2979663319 abstract "Environment-friendly nanosponges, having a high content of carboxyl groups, were synthesized by crosslinking β-cyclodextrin and linecaps, a highly soluble pea starch derivative, with citric acid in water. Additionally, pyromellitic nanosponges were prepared by reacting β-cyclodextrin and linecaps with pyromellitic dianhydride in dimethyl sulfoxide and used in comparison with the citric nanosponges. After ion-exchange of the carboxyl groups H+ with sodium ions, the ability of the nanosponges to sequester heavy metal cations was investigated. At a metal concentration of 500 ppm, the pyromellitate nanosponges exhibited a higher retention capacity than the citrate nanosponges. At lower metal concentrations (≤50 ppm) both the citrate and the pyromellitate nanosponges showed high retention capacities (up to 94% of the total amount of metal), while, in the presence of interfering sea water salts, the citrate nanosponges were able to selectively adsorb a significantly higher amount of heavy metals than the pyromellitate nanosponges, almost double in the case of Cu2+." @default.
- W2979663319 created "2019-10-18" @default.
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- W2979663319 date "2019-10-11" @default.
- W2979663319 modified "2023-10-07" @default.
- W2979663319 title "Eco-Friendly β-cyclodextrin and Linecaps Polymers for the Removal of Heavy Metals" @default.
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- W2979663319 doi "https://doi.org/10.3390/polym11101658" @default.
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