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- W2979893684 abstract "Azlactones, also known as oxazolones, possess multiple reactive sites, and are thus widely used as versatile class of reagents in organic synthesis, particularly in cycloaddition reactions for heterocycle synthesis. However, the use of azlactones as three‐member fragments in cycloaddition reactions/decarboxylation cascade were rarely explored. In this context, a metal‐free cycloaddition/decarboxylation reaction between azlactones and aryldiazonium salts has been achieved for the first time, which provides efficient and facile access to privileged 1,3,5‐trisubstituted 1,2,4‐triazoles. Notably, aryldiazonium salts serve as two‐nitrogen unit rather than the sources of aryl radicals in this transformation, which provides an alternative class of reagents for the construction of N‐heterocycles." @default.
- W2979893684 created "2019-10-18" @default.
- W2979893684 creator A5002341241 @default.
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- W2979893684 date "2019-10-24" @default.
- W2979893684 modified "2023-10-03" @default.
- W2979893684 title "Synthesis of Trisubstituted 1,2,4-Triazoles from Azlactones and Aryldiazonium Salts by a Cycloaddition/Decarboxylation Cascade" @default.
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- W2979893684 doi "https://doi.org/10.1002/ejoc.201901467" @default.
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