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• W2979905239 abstract "A Pd-catalyzed Hiyama cross-coupling reaction using SO2 is described. The use of silicon-based nucleophiles leads to the formation of allyl sulfones under mild conditions with a broad functional group tolerance. Control experiments coupled with DFT calculations shed light on the key steps of the reaction mechanism, revealing the crucial role of a transient sulfinate anion." @default.
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• W2979905239 date "2019-01-01" @default.
• W2979905239 modified "2023-10-18" @default.
• W2979905239 title "SO₂ conversion to sulfones: development and mechanistic insights of a sulfonylative Hiyama cross-coupling" @default.
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• W2979905239 doi "https://doi.org/10.1039/c9cc06858a" @default.
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