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- W2980047250 abstract "Nanothreads are one-dimensional sp3 hydrocarbons that pack within pseudohexagonal crystalline lattices. They are believed to lack long-range order along the thread axis and also lack interthread registry. Here we investigate the phase behavior of thiophene up to 35 GPa and establish a pressure-induced phase transition sequence that mirrors previous observations in low-temperature studies. Slow compression to 35 GPa results in the formation of a recoverable saturated product with a 2D monoclinic diffraction pattern along (0001) that agrees closely with atomistic simulations for single crystals of thiophene-derived nanothreads. Paradoxically, this lower-symmetry packing signals a higher degree of structural order since it must arise from constituents with a consistent azimuthal orientation about their shared axis. The simplicity of thiophene reaction pathways (with only four carbon atoms per ring) apparently yields the first nanothreads with orientational order, a striking outcome considering that a single point defect in a 1D system can disrupt long-range structural order." @default.
- W2980047250 created "2019-10-18" @default.
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- W2980047250 date "2019-10-11" @default.
- W2980047250 modified "2023-10-01" @default.
- W2980047250 title "Evidence for Orientational Order in Nanothreads Derived from Thiophene" @default.
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- W2980047250 doi "https://doi.org/10.1021/acs.jpclett.9b02546" @default.
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