Matches in SemOpenAlex for { <https://semopenalex.org/work/W2980152887> ?p ?o ?g. }
- W2980152887 abstract "Abstract The crystal structures of the charge‐transfer (CT) cocrystals formed by the π‐electron acceptor 1,3,4,5,7,8‐hexafluoro‐11,11,12,12‐tetracyanonaphtho‐2,6‐quinodimethane (F 6 TNAP) with the planar π‐electron‐donor molecules triphenylene (TP), benzo[ b ]benzo[4,5]thieno[2,3‐ d ]thiophene (BTBT), benzo[1,2‐ b :4,5‐ b ′]dithiophene (BDT), pyrene (PY), anthracene (ANT), and carbazole (CBZ) have been determined using single‐crystal X‐ray diffraction (SCXRD), along with those of two polymorphs of F 6 TNAP. All six cocrystals exhibit 1:1 donor/acceptor stoichiometry and adopt mixed‐stacking motifs. Cocrystals based on BTBT and CBZ π‐electron donor molecules exhibit brickwork packing, while the other four CT cocrystals show herringbone‐type crystal packing. Infrared spectroscopy, molecular geometries determined by SCXRD, and electronic structure calculations indicate that the extent of ground‐state CT in each cocrystal is small. Density functional theory calculations predict large conduction bandwidths and, consequently, low effective masses for electrons for all six CT cocrystals, while the TP‐, BDT‐, and PY‐based cocrystals are also predicted to have large valence bandwidths and low effective masses for holes. Charge‐carrier mobility values are obtained from space‐charge limited current (SCLC) measurements and field‐effect transistor measurements, with values exceeding 1 cm 2 V −1 s 1 being estimated from SCLC measurements for BTBT:F 6 TNAP and CBZ:F 6 TNAP cocrystals." @default.
- W2980152887 created "2019-10-18" @default.
- W2980152887 creator A5005129037 @default.
- W2980152887 creator A5010623694 @default.
- W2980152887 creator A5011204469 @default.
- W2980152887 creator A5017344143 @default.
- W2980152887 creator A5022996695 @default.
- W2980152887 creator A5030742588 @default.
- W2980152887 creator A5045853606 @default.
- W2980152887 creator A5049912304 @default.
- W2980152887 creator A5050152527 @default.
- W2980152887 creator A5055677892 @default.
- W2980152887 creator A5056633634 @default.
- W2980152887 creator A5064450543 @default.
- W2980152887 creator A5076609099 @default.
- W2980152887 creator A5089729394 @default.
- W2980152887 date "2019-10-09" @default.
- W2980152887 modified "2023-10-15" @default.
- W2980152887 title "Charge‐Transport Properties of F <sub>6</sub> TNAP‐Based Charge‐Transfer Cocrystals" @default.
- W2980152887 cites W1969360633 @default.
- W2980152887 cites W1972365867 @default.
- W2980152887 cites W1975280653 @default.
- W2980152887 cites W1976342669 @default.
- W2980152887 cites W1983084926 @default.
- W2980152887 cites W1984750063 @default.
- W2980152887 cites W1989955778 @default.
- W2980152887 cites W2001141154 @default.
- W2980152887 cites W2005596689 @default.
- W2980152887 cites W2007049305 @default.
- W2980152887 cites W2013359407 @default.
- W2980152887 cites W2018059080 @default.
- W2980152887 cites W2025235950 @default.
- W2980152887 cites W2026371249 @default.
- W2980152887 cites W2027828281 @default.
- W2980152887 cites W2029833660 @default.
- W2980152887 cites W2032301702 @default.
- W2980152887 cites W2034103159 @default.
- W2980152887 cites W2034555969 @default.
- W2980152887 cites W2039194884 @default.
- W2980152887 cites W2039974132 @default.
- W2980152887 cites W2046704339 @default.
- W2980152887 cites W2052052818 @default.
- W2980152887 cites W2057870893 @default.
- W2980152887 cites W2059205366 @default.
- W2980152887 cites W2061164436 @default.
- W2980152887 cites W2063529487 @default.
- W2980152887 cites W2065224987 @default.
- W2980152887 cites W2084367355 @default.
- W2980152887 cites W2090084145 @default.
- W2980152887 cites W2102003414 @default.
- W2980152887 cites W2115590468 @default.
- W2980152887 cites W2121124343 @default.
- W2980152887 cites W2125059109 @default.
- W2980152887 cites W2132454074 @default.
- W2980152887 cites W2147156872 @default.
- W2980152887 cites W2163986271 @default.
- W2980152887 cites W2164018295 @default.
- W2980152887 cites W2165596800 @default.
- W2980152887 cites W2271606783 @default.
- W2980152887 cites W2316126845 @default.
- W2980152887 cites W2322613269 @default.
- W2980152887 cites W2327674255 @default.
- W2980152887 cites W2332402630 @default.
- W2980152887 cites W2332995085 @default.
- W2980152887 cites W2334982399 @default.
- W2980152887 cites W2344497076 @default.
- W2980152887 cites W2397792303 @default.
- W2980152887 cites W2482810354 @default.
- W2980152887 cites W2517358235 @default.
- W2980152887 cites W2520524362 @default.
- W2980152887 cites W2560319792 @default.
- W2980152887 cites W2563527429 @default.
- W2980152887 cites W2581107686 @default.
- W2980152887 cites W2593964856 @default.
- W2980152887 cites W2610264818 @default.
- W2980152887 cites W2624900231 @default.
- W2980152887 cites W2739127947 @default.
- W2980152887 cites W2756809259 @default.
- W2980152887 cites W2767626850 @default.
- W2980152887 cites W2778076912 @default.
- W2980152887 cites W2782790640 @default.
- W2980152887 cites W2786287726 @default.
- W2980152887 cites W2790698330 @default.
- W2980152887 cites W2806940223 @default.
- W2980152887 cites W2885513136 @default.
- W2980152887 cites W2907321445 @default.
- W2980152887 cites W2921075665 @default.
- W2980152887 cites W2947576990 @default.
- W2980152887 cites W3099189637 @default.
- W2980152887 cites W3099638761 @default.
- W2980152887 cites W3101415803 @default.
- W2980152887 cites W4211154773 @default.
- W2980152887 cites W696645 @default.
- W2980152887 doi "https://doi.org/10.1002/adfm.201904858" @default.
- W2980152887 hasPublicationYear "2019" @default.
- W2980152887 type Work @default.
- W2980152887 sameAs 2980152887 @default.
- W2980152887 citedByCount "33" @default.
- W2980152887 countsByYear W29801528872020 @default.
- W2980152887 countsByYear W29801528872021 @default.