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- W2980212999 abstract "A new one-dimensional (1D) antiferromagnetic transition metal hybrid fluoride CoF2(H2O)2(pyz) (pyz = pyrazine) together with two new isostructural MF2(H2O)2(pyz) (M = Ni2+, Zn2+) have been successfully synthesized by the hydrothermal method. Their structures were determined by single crystal X-ray diffraction and they all crystallize in the same space group of C2/m. The magnetic property of CoF2(H2O)2(pyz) 1 was measured and discussed. The Weiss constant of -20.6 K indicates dominant antiferromagnetic interaction and the effective magnetic moment of about 5.66 μB suggests large unquenched orbital contribution and anisotropy in 1. The quantum fluctuations in the quasi-1D antiferromagnet of 1 prevent the appearance of long range magnetic order until 2.9 K, suggesting good 1D magnetism." @default.
- W2980212999 created "2019-10-18" @default.
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- W2980212999 date "2019-10-11" @default.
- W2980212999 modified "2023-10-12" @default.
- W2980212999 title "Synthesis and characterization of a new quasi-one-dimensional antiferromagnet CoF2(H2O)2(pyrazine)" @default.
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- W2980212999 doi "https://doi.org/10.1007/s40843-019-1198-3" @default.
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