Matches in SemOpenAlex for { <https://semopenalex.org/work/W2980232279> ?p ?o ?g. }
- W2980232279 endingPage "H729" @default.
- W2980232279 startingPage "H721" @default.
- W2980232279 abstract "This study evaluated the ion transport properties of 1-ethyl-3-methylimidazolium acetate (EMIAc)-based solutions containing additional acetonitrile (AN), H2O, and up to 3.0 wt-% carbohydrate solutes. Solution ion conductivity was directly measured via frequency response, and ion self-diffusivity coefficients determined via pulsed-field gradient spin-echo (PGSE) NMR. These data combined to determine solution ionicity. Multiple linear regression analysis shows ionicity is primarily impacted by the added neutral solvent, and weakly impacted by temperature. Addition of equimolar AN or H2O increases both cation and anion self-diffusivity (D+ and D−, respectively), and each of these solvent systems decreases the D+/D− quotient. Addition of carbohydrate solutes decreases cation and anion self-diffusivity, but solute additions slightly increase the D+/D− quotient. Our observation that carbohydrate solutes reduce Ac self-diffusivity by a greater fraction than EMI supports the general assertion that acetate anions are more heavily involved in solvating cellulose than EMI cations. Finally, EMIAc solutions containing microcrystalline cellulose (MCC) were evaluated by NMR spin-lattice relaxation (T1) measurements. These T1 data reveal the microviscosity of EMIAc:MCC solutions is virtually unchanged with addition of up to 3.0 wt-% solute, in agreement with the ion transport properties measured at the same scale." @default.
- W2980232279 created "2019-10-18" @default.
- W2980232279 creator A5014664773 @default.
- W2980232279 creator A5021622549 @default.
- W2980232279 creator A5027347845 @default.
- W2980232279 creator A5032248455 @default.
- W2980232279 creator A5032962435 @default.
- W2980232279 creator A5033812061 @default.
- W2980232279 creator A5039125383 @default.
- W2980232279 creator A5060558971 @default.
- W2980232279 creator A5067164917 @default.
- W2980232279 creator A5068932487 @default.
- W2980232279 date "2019-01-01" @default.
- W2980232279 modified "2023-10-17" @default.
- W2980232279 title "Evaluating the Ion Transport of 1-Ethyl-3-Methylimidazolium Acetate Solutions Containing Carbohydrate Solutes" @default.
- W2980232279 cites W117172470 @default.
- W2980232279 cites W1600292521 @default.
- W2980232279 cites W1965200916 @default.
- W2980232279 cites W1970364308 @default.
- W2980232279 cites W1983496093 @default.
- W2980232279 cites W1993547914 @default.
- W2980232279 cites W2013898091 @default.
- W2980232279 cites W2015942244 @default.
- W2980232279 cites W2016677878 @default.
- W2980232279 cites W2022253452 @default.
- W2980232279 cites W2023828347 @default.
- W2980232279 cites W2039639599 @default.
- W2980232279 cites W2043768024 @default.
- W2980232279 cites W2047371385 @default.
- W2980232279 cites W2047505239 @default.
- W2980232279 cites W2050948151 @default.
- W2980232279 cites W2053326407 @default.
- W2980232279 cites W2062932961 @default.
- W2980232279 cites W2063613247 @default.
- W2980232279 cites W2068100174 @default.
- W2980232279 cites W2093177326 @default.
- W2980232279 cites W2094106578 @default.
- W2980232279 cites W2095395663 @default.
- W2980232279 cites W2116902039 @default.
- W2980232279 cites W2118064770 @default.
- W2980232279 cites W2122195686 @default.
- W2980232279 cites W2124597819 @default.
- W2980232279 cites W2125519621 @default.
- W2980232279 cites W2131904845 @default.
- W2980232279 cites W2139413502 @default.
- W2980232279 cites W2142639540 @default.
- W2980232279 cites W2147655148 @default.
- W2980232279 cites W2165861896 @default.
- W2980232279 cites W2315756290 @default.
- W2980232279 cites W2327992839 @default.
- W2980232279 cites W2440030356 @default.
- W2980232279 cites W2493787350 @default.
- W2980232279 cites W2510093375 @default.
- W2980232279 cites W2520436527 @default.
- W2980232279 cites W2755259238 @default.
- W2980232279 cites W2775704722 @default.
- W2980232279 cites W2800238134 @default.
- W2980232279 cites W2913587979 @default.
- W2980232279 cites W2913987875 @default.
- W2980232279 cites W2917048542 @default.
- W2980232279 cites W2917178587 @default.
- W2980232279 cites W2931017576 @default.
- W2980232279 cites W4234326489 @default.
- W2980232279 cites W4239450165 @default.
- W2980232279 cites W4376595649 @default.
- W2980232279 doi "https://doi.org/10.1149/2.0971914jes" @default.
- W2980232279 hasPublicationYear "2019" @default.
- W2980232279 type Work @default.
- W2980232279 sameAs 2980232279 @default.
- W2980232279 citedByCount "5" @default.
- W2980232279 countsByYear W29802322792020 @default.
- W2980232279 countsByYear W29802322792021 @default.
- W2980232279 countsByYear W29802322792022 @default.
- W2980232279 crossrefType "journal-article" @default.
- W2980232279 hasAuthorship W2980232279A5014664773 @default.
- W2980232279 hasAuthorship W2980232279A5021622549 @default.
- W2980232279 hasAuthorship W2980232279A5027347845 @default.
- W2980232279 hasAuthorship W2980232279A5032248455 @default.
- W2980232279 hasAuthorship W2980232279A5032962435 @default.
- W2980232279 hasAuthorship W2980232279A5033812061 @default.
- W2980232279 hasAuthorship W2980232279A5039125383 @default.
- W2980232279 hasAuthorship W2980232279A5060558971 @default.
- W2980232279 hasAuthorship W2980232279A5067164917 @default.
- W2980232279 hasAuthorship W2980232279A5068932487 @default.
- W2980232279 hasConcept C113196181 @default.
- W2980232279 hasConcept C121332964 @default.
- W2980232279 hasConcept C139932579 @default.
- W2980232279 hasConcept C145148216 @default.
- W2980232279 hasConcept C147789679 @default.
- W2980232279 hasConcept C148093993 @default.
- W2980232279 hasConcept C178790620 @default.
- W2980232279 hasConcept C179104552 @default.
- W2980232279 hasConcept C185592680 @default.
- W2980232279 hasConcept C2777118752 @default.
- W2980232279 hasConcept C2779251873 @default.
- W2980232279 hasConcept C2780471494 @default.
- W2980232279 hasConcept C37668627 @default.
- W2980232279 hasConcept C41625074 @default.