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• W2980251049 abstract "The Diels–Alder reactivity of 4,4-difluoro-3,5-diphenyl-4H-pyrazole was investigated experimentally and computationally with endo-bicyclo[6.1.0]non-4-yne. The computationally predicted rate enhancement from hyperconjugative antiaromaticity induced by fluorination of cyclopentadienes at the 5-position extends to five-membered heterocyclic dienes containing a saturated center. 4,4-Difluoro-4H-pyrazoles are new electron-deficient dienes with rapid reactivities toward strained alkynes." @default.
• W2980251049 created "2019-10-18" @default.
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• W2980251049 date "2019-10-07" @default.
• W2980251049 modified "2023-10-17" @default.
• W2980251049 title "Hyperconjugative Antiaromaticity Activates 4<i>H</i>-Pyrazoles as Inverse-Electron-Demand Diels–Alder Dienes" @default.
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• W2980251049 doi "https://doi.org/10.1021/acs.orglett.9b03351" @default.
• W2980251049 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/7015664" @default.
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