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• W2980261010 startingPage "117576" @default.
• W2980261010 abstract "In this report we present a UV-Vis spectroscopic study of the pH dependent optical properties of 4,4'-azobenzene dicarboxylic acid in aqueous solution. A combination of chemical (acid-base) and light stimuli is combined to demonstrate that the system undergoes two types of optical switching cycles. At neutral pH the azobenzene undergoes photo-induced cis-trans isomerisation. Upon pH reduction the UV-Vis spectra show changes consistent with aggregation of the azobenzene photo-switch. The photo-responsive behaviour is dependent on the pH and conformation of the azobenzene. The optical properties of the system are dependent on the mode of pH reduction and the isomeric cis/trans composition of the photo-switch, showing hierarchical control of self-assembly." @default.
• W2980261010 created "2019-10-18" @default.
• W2980261010 creator A5023181787 @default.
• W2980261010 creator A5047094134 @default.
• W2980261010 date "2020-02-01" @default.
• W2980261010 modified "2023-10-16" @default.
• W2980261010 title "Spectroscopic study of the pH dependence of the optical properties of a water-soluble molecular photo-switch" @default.
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• W2980261010 doi "https://doi.org/10.1016/j.saa.2019.117576" @default.
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