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- W2980290823 endingPage "8505" @default.
- W2980290823 startingPage "8501" @default.
- W2980290823 abstract "Highly enantioselective cascade double allylations of 1-alkyl-3-alkylindolin-2-imine hydrochlorides with (E)-but-2-ene-1,4-diyl dimethyl dicarbonate leading to tetrahydropyrrolo[2,3-b]indoles with an all-carbon quaternary stereocenter have been developed. This transformation was catalyzed by an iridium catalyst together with our developed chiral cyclic phosphoramidite ligand. The method shows some advantages including an operationally simple protocol, fast reaction, and excellent diastereoselectivity and enantioselectivity. Furthermore, reduction of the obtained products with diisobutyl aluminum hydride provided the pyrrolidinoindolines with three chiral centers in high yields with excellent diastereoselectivity and enantioselectivity." @default.
- W2980290823 created "2019-10-18" @default.
- W2980290823 creator A5014562090 @default.
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- W2980290823 creator A5033898587 @default.
- W2980290823 creator A5078804921 @default.
- W2980290823 creator A5085550693 @default.
- W2980290823 date "2019-10-08" @default.
- W2980290823 modified "2023-10-16" @default.
- W2980290823 title "Highly Enantioselective Iridium-Catalyzed Cascade Double Allylation Strategy: Synthesis of Pyrrolidinoindolines with an All-Carbon Quaternary Stereocenter" @default.
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- W2980290823 doi "https://doi.org/10.1021/acs.orglett.9b03382" @default.
- W2980290823 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31591895" @default.
- W2980290823 hasPublicationYear "2019" @default.
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