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- W2980340436 abstract "Abstract Weakly σ-donating phosphines bearing a hexafluorocyclopentene skeleton were synthesized. The 1JPSe coupling constants of selenides of the fluorinated phosphines revealed substantially decreased s-character of the phosphorus lone pair orbitals of the fluorinated phosphines, indicating their weak σ-donating ability. Au(I), Pd(II) and Pt(II) complexes bearing the fluorinated phosphines showed moderate catalytic activity in the hydration and hydroarylation of alkynes." @default.
- W2980340436 created "2019-10-25" @default.
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- W2980340436 date "2019-01-01" @default.
- W2980340436 modified "2023-10-17" @default.
- W2980340436 title "Phosphines featuring a hexafluorocyclopentene skeleton: Synthesis, coordination properties, and applications for Lewis-acidic transition-metal catalysts" @default.
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- W2980340436 doi "https://doi.org/10.1016/j.rechem.2019.100008" @default.
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