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- W2980490321 abstract "Copolymerization of 1,3-butadiene with four 1-substituted 1,3-diene comonomers bearing amino and alkyoxy groups by a Ziegler-Natta iron(iii) catalytic system to access in-chain functionalized syndiotactic 1,2-polybutadiene is reported herein. The polar comonomer content can be easily regulated by varying the comonomer loadings or polymerization conditions, affording functionalized syndiotactic 1,2-polybutadiene with different amounts of functionalities. The incorporation of a polar comonomer showed little influence on the 1,2-content and stereoregularity of the resulting polymers, giving a 1,2-structure as high as ∼85% and an rrrr pentad of 81.0%. Significantly improved surface properties of the polymers was obtained after incorporation of polar comonomer, as revealed from the remarkably decreased water contact angles." @default.
- W2980490321 created "2019-10-25" @default.
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- W2980490321 date "2019-01-01" @default.
- W2980490321 modified "2023-10-14" @default.
- W2980490321 title "In-chain functionalized syndiotactic 1,2-polybutadiene by a Ziegler–Natta iron(<scp>iii</scp>) catalytic system" @default.
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- W2980490321 doi "https://doi.org/10.1039/c9ra06499k" @default.
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