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- W2980696033 abstract "Direct synthesis of N-(hetero)arylated heteroarenes has been realized through Cu-mediated C-N coupling of NH azaheterocycles with aryl C-H bonds under aerobic conditions. This method features a broad scope of both heterocyclic arenes (pyridine, quinoline, pyrazole, imidazole, furan, thiophene, benzofuran, and indole) and NH azaheterocycles (imidazole, pyrazole, indole, azindole, purine, indazole, benzimidazole, pyridone, carbazole), providing a versatile method for the synthesis of pharmaceutically important N-(hetero)arylated heteroarenes. The versatility of this reaction was further demonstrated through late-stage modification of marketed drugs and the synthesis of a key intermediate for accessing a class of angiotensin II receptor 1 antagonists." @default.
- W2980696033 created "2019-10-25" @default.
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- W2980696033 date "2019-11-08" @default.
- W2980696033 modified "2023-09-27" @default.
- W2980696033 title "Cu‐Mediated Amination of (Hetero)Aryl C−H bonds with NH Azaheterocycles" @default.
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- W2980696033 doi "https://doi.org/10.1002/anie.201910395" @default.
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