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- W2980822992 abstract "Blue prismatic crystals of mononuclear [Cu II (O 2 CH) 2 (Py) 3 ] (Py = pyridine, C 5 H 5 N), 1 , were prepared from reaction solution containing dry pyridine and dinuclear [Cu 2 II (O 2 CH) 4 (Py) 2 ]. When a portion of solution together with crystals was exposed to air moisture, crystals of 1 dissolved in mother liquid. Simultaneously, blue needles of 2 , i.e. covalently linked one-dimensional chain structure with formula [Cu(O 2 CH) 2 (Py) 2 ] n · n H 2 O, grew out of the solution. The process lasted few minutes and was observed under optical microscope. The conversion from 1 to 2 takes place also outside of solution in the solid state. Single crystal X-ray diffraction data were collected at 150 K for 1 and after that for 2 , originating from the same reaction solution. This paper reports the structures of both compounds. Alternative synthesis method of 2 arising from a mixture of copper methanoate and pyridine is also reported." @default.
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- W2980822992 date "2019-12-18" @default.
- W2980822992 modified "2023-09-23" @default.
- W2980822992 title "Copper(II) Coordination Compounds with Methanoato and Pyridine Ligands: Conversion from Mononuclear to Polynuclear in the Presence of Moisture" @default.
- W2980822992 doi "https://doi.org/10.17344/acsi.2019.5484" @default.
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