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- W2980879937 abstract "Abstract Oxidation of indoles is a fundamental organic transformation to deliver a variety of synthetically and pharmaceutically valuable nitrogen-containing compounds. Prior methods require the use of either organic oxidants ( meta -chloroperoxybenzoic acid, N-bromosuccinimide, t -BuOCl) or stoichiometric toxic transition metals [Pb(OAc) 4 , OsO 4 , CrO 3 ], which produced oxidant-derived by-products that are harmful to human health, pollute the environment and entail immediate purification. A general catalysis protocol using safer oxidants (H 2 O 2 , oxone, O 2 ) is highly desirable. Herein, we report a unified, efficient halide catalysis for three oxidation reactions of indoles using oxone as the terminal oxidant, namely oxidative rearrangement of tetrahydro-β-carbolines, indole oxidation to 2-oxindoles, and Witkop oxidation. This halide catalysis protocol represents a general, green oxidation method and is expected to be used widely due to several advantageous aspects including waste prevention, less hazardous chemical synthesis, and sustainable halide catalysis." @default.
- W2980879937 created "2019-10-25" @default.
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- W2980879937 date "2019-10-18" @default.
- W2980879937 modified "2023-10-17" @default.
- W2980879937 title "Green oxidation of indoles using halide catalysis" @default.
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- W2980879937 doi "https://doi.org/10.1038/s41467-019-12768-4" @default.
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