FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2980883688> ?p ?o ?g. }

• W2980883688 endingPage "4721" @default.
• W2980883688 startingPage "4704" @default.
• W2980883688 abstract "We conducted large scale molecular dynamics simulations to understand the effects of size, shape and volume fraction of additive nanoparticles on the crystallization of nanocomposite polymers. We used spherical and cubic gold nanoparticles of various sizes ranging from 2 to 8 nm to create hexacontane (C60H122)-gold nanocomposites at various volume fractions of 0.84-19.27%. We show that, regardless of the shape, decreasing the size of particles at the same volume fraction results in decreased final crystallinity. Similarly, for the same particle size, increasing the volume fraction causes a decrease in the crystal growth rate and final crystallinity. We demonstrate that this is a confinement induced phenomenon, and the free interparticle space captures the combined effects of particle size and volume fraction. If this free space is smaller than the extended length of the molecule or the characteristic size of the crystal lamella thickness of the polymer, significant slow-down in crystallinity will emerge. In this confinement limit, the interparticle free space controls the crystal growth rate and final crystallinity. We have developed the equations that predict the critical volume fraction (φcr) for a given size or critical size (Dcr) for a given volume fraction. For φ > φcr or D < Dcr, one would expect confinement induced retardation of crystallization. We also show that cubic particles result in a higher growth rate and crystallinity in comparison to spherical particles, purely due to their shape. Furthermore, cubic particles due to flat surfaces lead to distinct two-tier crystallisation kinetics manifested by enhanced crystallization at the early stage of crystallization, followed by slow crystallization due to confinement effects. This two-tier crystallization is more distinct at higher volume fractions. For spherical particles, however, this two-tier crystallization is almost absent and molecular crystallization near the particle is frustrated by the curved shape of the nanoparticle." @default.
• W2980883688 created "2019-10-25" @default.
• W2980883688 creator A5020256775 @default.
• W2980883688 creator A5030954100 @default.
• W2980883688 date "2019-01-01" @default.
• W2980883688 modified "2023-10-18" @default.
• W2980883688 title "Unravelling the effects of size, volume fraction and shape of nanoparticle additives on crystallization of nanocomposite polymers" @default.
• W2980883688 cites W1971873005 @default.
• W2980883688 cites W1972006232 @default.
• W2980883688 cites W1988831202 @default.
• W2980883688 cites W1990492888 @default.
• W2980883688 cites W1994106361 @default.
• W2980883688 cites W1995048986 @default.
• W2980883688 cites W1999928247 @default.
• W2980883688 cites W2008540777 @default.
• W2980883688 cites W2011350314 @default.
• W2980883688 cites W2022286110 @default.
• W2980883688 cites W2024908520 @default.
• W2980883688 cites W2036694628 @default.
• W2980883688 cites W2038275767 @default.
• W2980883688 cites W2040323875 @default.
• W2980883688 cites W2040552744 @default.
• W2980883688 cites W2041799287 @default.
• W2980883688 cites W2053378222 @default.
• W2980883688 cites W2077732073 @default.
• W2980883688 cites W2080253977 @default.
• W2980883688 cites W2112743813 @default.
• W2980883688 cites W2113182435 @default.
• W2980883688 cites W2142292375 @default.
• W2980883688 cites W2163206126 @default.
• W2980883688 cites W2316453543 @default.
• W2980883688 cites W2332320557 @default.
• W2980883688 cites W2584517811 @default.
• W2980883688 cites W2600039799 @default.
• W2980883688 cites W2622997001 @default.
• W2980883688 cites W2625704920 @default.
• W2980883688 cites W2734360736 @default.
• W2980883688 cites W2897659037 @default.
• W2980883688 cites W2922592028 @default.
• W2980883688 cites W2773057337 @default.
• W2980883688 doi "https://doi.org/10.1039/c9na00525k" @default.
• W2980883688 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36133133" @default.
• W2980883688 hasPublicationYear "2019" @default.
• W2980883688 type Work @default.
• W2980883688 sameAs 2980883688 @default.
• W2980883688 citedByCount "28" @default.
• W2980883688 countsByYear W29808836882020 @default.
• W2980883688 countsByYear W29808836882021 @default.
• W2980883688 countsByYear W29808836882022 @default.
• W2980883688 countsByYear W29808836882023 @default.
• W2980883688 crossrefType "journal-article" @default.
• W2980883688 hasAuthorship W2980883688A5020256775 @default.
• W2980883688 hasAuthorship W2980883688A5030954100 @default.
• W2980883688 hasBestOaLocation W29808836881 @default.
• W2980883688 hasConcept C110530677 @default.
• W2980883688 hasConcept C111368507 @default.
• W2980883688 hasConcept C121332964 @default.
• W2980883688 hasConcept C127313418 @default.
• W2980883688 hasConcept C127413603 @default.
• W2980883688 hasConcept C155672457 @default.
• W2980883688 hasConcept C159985019 @default.
• W2980883688 hasConcept C171250308 @default.
• W2980883688 hasConcept C187530423 @default.
• W2980883688 hasConcept C192562407 @default.
• W2980883688 hasConcept C199360897 @default.
• W2980883688 hasConcept C203036418 @default.
• W2980883688 hasConcept C20556612 @default.
• W2980883688 hasConcept C2778517922 @default.
• W2980883688 hasConcept C2781285689 @default.
• W2980883688 hasConcept C41008148 @default.
• W2980883688 hasConcept C42360764 @default.
• W2980883688 hasConcept C46275449 @default.
• W2980883688 hasConcept C521977710 @default.
• W2980883688 hasConcept C65590680 @default.
• W2980883688 hasConcept C92880739 @default.
• W2980883688 hasConcept C97355855 @default.
• W2980883688 hasConceptScore W2980883688C110530677 @default.
• W2980883688 hasConceptScore W2980883688C111368507 @default.
• W2980883688 hasConceptScore W2980883688C121332964 @default.
• W2980883688 hasConceptScore W2980883688C127313418 @default.
• W2980883688 hasConceptScore W2980883688C127413603 @default.
• W2980883688 hasConceptScore W2980883688C155672457 @default.
• W2980883688 hasConceptScore W2980883688C159985019 @default.
• W2980883688 hasConceptScore W2980883688C171250308 @default.
• W2980883688 hasConceptScore W2980883688C187530423 @default.
• W2980883688 hasConceptScore W2980883688C192562407 @default.
• W2980883688 hasConceptScore W2980883688C199360897 @default.
• W2980883688 hasConceptScore W2980883688C203036418 @default.
• W2980883688 hasConceptScore W2980883688C20556612 @default.
• W2980883688 hasConceptScore W2980883688C2778517922 @default.
• W2980883688 hasConceptScore W2980883688C2781285689 @default.
• W2980883688 hasConceptScore W2980883688C41008148 @default.
• W2980883688 hasConceptScore W2980883688C42360764 @default.
• W2980883688 hasConceptScore W2980883688C46275449 @default.
• W2980883688 hasConceptScore W2980883688C521977710 @default.
• W2980883688 hasConceptScore W2980883688C65590680 @default.
• W2980883688 hasConceptScore W2980883688C92880739 @default.
• W2980883688 hasConceptScore W2980883688C97355855 @default.

• next