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- W2980931434 abstract "Abstract Atom‐transfer radical addition (ATRA) reactions have gained a strong foothold in organic synthesis by virtue of their operational simplicity, synthetic versatility, and perfect atom economy. A rich chemical space can be accessed through clever combinations of the simple starting materials. Many variations of this general motif have been reported. However, the vast majority involve the addition of an organic halide across a C=C double bond, resulting in the formation of 1,2‐bifunctional products. This report introduces a significant expansion of this general reactivity concept to give 1,3‐bifunctional adducts through the combination of 1,1‐ATRA to a carbenoid and 1,2‐ATRA to an alkyne. Both processes operate under mild conditions (RT, 5 h) with the same commercial catalyst (CoBr 2 , dppbz)." @default.
- W2980931434 created "2019-10-25" @default.
- W2980931434 creator A5023316554 @default.
- W2980931434 creator A5038469470 @default.
- W2980931434 creator A5046541409 @default.
- W2980931434 date "2019-10-15" @default.
- W2980931434 modified "2023-10-16" @default.
- W2980931434 title "A Carbene‐Extended ATRA Reaction" @default.
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- W2980931434 doi "https://doi.org/10.1002/anie.201909872" @default.
- W2980931434 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/6900008" @default.
- W2980931434 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31613415" @default.
- W2980931434 hasPublicationYear "2019" @default.
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