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- W2980969433 endingPage "417" @default.
- W2980969433 startingPage "409" @default.
- W2980969433 abstract "Riboflavin-derived photocatalysts have been extensively studied in the context of alcohol oxidation. However, to date, the scope of this catalytic methodology has been limited to benzyl alcohols. In this work, mechanistic understanding of flavin-catalyzed oxidation reactions, in either the absence or presence of thiourea as a cocatalyst, was obtained. The mechanistic insights enabled development of an electrochemically driven photochemical oxidation of primary and secondary aliphatic alcohols using a pair of flavin and dialkylthiourea catalysts. Electrochemistry makes it possible to avoid using O2 and an oxidant and generating H2 O2 as a byproduct, both of which oxidatively degrade thiourea under the reaction conditions. This modification unlocks a new mechanistic pathway in which the oxidation of unactivated alcohols is achieved by thiyl radical mediated hydrogen-atom abstraction." @default.
- W2980969433 created "2019-10-25" @default.
- W2980969433 creator A5044877276 @default.
- W2980969433 creator A5055475155 @default.
- W2980969433 creator A5074708328 @default.
- W2980969433 date "2019-11-18" @default.
- W2980969433 modified "2023-10-16" @default.
- W2980969433 title "Electrochemistry Broadens the Scope of Flavin Photocatalysis: Photoelectrocatalytic Oxidation of Unactivated Alcohols" @default.
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