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- W2981123898 abstract "For the first time, CO2-expanded bio-based liquids were reported as novel and sustainable solvents for biocatalysis. Herein, it was found that by expansion with CO2, 2-methyltetrahydrofuran (MeTHF), and other bio-based liquids, which were not favorable solvents for immobilized Candida antarctica lipase B (Novozym 435) catalyzed transesterification, were tuned into excellent reaction media. Especially, for the kinetic resolution of challenging bulky secondary substrates such as rac-1-adamantylethanol, the lipase displayed very high activity with excellent enantioselectivity (E value > 200) in CO2-expanded MeTHF (MeTHF concentration 10% v/v, 6 MPa), whereas there was almost no activity observed in conventional organic solvents." @default.
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- W2981123898 date "2019-11-01" @default.
- W2981123898 modified "2023-09-25" @default.
- W2981123898 title "The genetic monitoring of natural and agroecosystem" @default.
- W2981123898 doi "https://doi.org/10.1016/j.jbiotec.2019.05.220" @default.
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