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- W2981447065 endingPage "14973" @default.
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- W2981447065 abstract "Upon treatment with a combination of HFIP and an organic sulfonic acid, alkenes behave as Brønsted bases and protonate to give carbocations which can be trapped by electron-rich arenes. The reaction constitutes a Friedel–Crafts hydroarylation which proceeds with Markovnikov selectivity and is orthogonal to traditional metal-catalyzed processes. Intermolecular transfer hydrogenation and hydrothiolation under analogous conditions are also demonstrated." @default.
- W2981447065 created "2019-11-01" @default.
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- W2981447065 date "2019-10-21" @default.
- W2981447065 modified "2023-10-18" @default.
- W2981447065 title "Hydroarylation of Alkenes by Protonation/Friedel–Crafts Trapping: HFIP-Mediated Access to Per-aryl Quaternary Stereocenters" @default.
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- W2981447065 doi "https://doi.org/10.1021/acs.joc.9b02393" @default.
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