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- W2981738215 endingPage "119227" @default.
- W2981738215 startingPage "119227" @default.
- W2981738215 abstract "Two new compounds [Fe2(CO)4(μ-naphthalene-2-thiolate)2(μ-dppe)] 1 and [Fe2(CO)4(μ-naphthalene-2-thiolate)2(μ-DPEPhos)] 2 with chelating phosphine ligands were synthesized and characterized {dppe = 1,2-Bis(diphenylphosphino)ethane and DPEPhos = (Oxydi-2, 1-phenylene)bis(diphenylphosphine)}. The bridging coordination mode of the diphosphine ligand in complex 1 was confirmed by X-ray crystallography. Complexes 1 and 2 were further evaluated as catalysts for the hydrogen evolution reaction (HER) by electrochemical investigations. Complex 1 showed better stability whereas complex 2 degraded in the presence of acids." @default.
- W2981738215 created "2019-11-01" @default.
- W2981738215 creator A5049688120 @default.
- W2981738215 creator A5067386469 @default.
- W2981738215 creator A5076936031 @default.
- W2981738215 date "2020-02-01" @default.
- W2981738215 modified "2023-10-03" @default.
- W2981738215 title "Structural and HER studies of diphosphine-monothiolate complexes [Fe2(CO)4(μ-naphthalene-2-thiolate)2(μ-dppe)] and [Fe2(CO)4(μ-naphthalene-2-thiolate)2(μ-DPEPhos)]" @default.
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