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- W2981836427 abstract "Abstract The synthesis of cyclic hydroxy-phosphonate bearing polybutenes using ring-opening metathesis polymerization (ROMP) has been accomplished. Reacting cyclooct-5-ene-1,2-diol with diethyl chlorophosphate gave a new monomer, cyclic hydroxy-phosphonate functional cyclooctene (IV). A kinetic study of the ROMP of (IV) using Grubb’s second generation (G2) and third generation (G3) catalysts was carried out using 1H NMR spectroscopy. The G2 catalyst was more efficient than G3 and gave ~85% conversion over 1 h at ambient temperature. Kinetic constants are also calculated and reported. At the same time, cyclooctadiene (COD) was introduced as the co-monomer in a co-polymerization route, and the characterization and thermal properties of the resulting product were investigated using NMR, GPC, TGA and DSC. Homopolymer IV gave a 37% char yield at 600 °C under nitrogen. Upon increasing the phosphorus content in the co-polymer also enhanced the thermal properties. This polymer has also been explored for Cu purification under both liquid-liquid and solid liquid extraction." @default.
- W2981836427 created "2019-11-01" @default.
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- W2981836427 date "2019-12-01" @default.
- W2981836427 modified "2023-09-27" @default.
- W2981836427 title "The synthesis of cyclic hydroxy-phosphonate bearing polybutene using ROMP" @default.
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- W2981836427 doi "https://doi.org/10.1016/j.eurpolymj.2019.109318" @default.
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