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- W2982018169 abstract "A conjecture concerning the asymptotic behavior of the outermost orbital in atomic configurations with a single electron outside an N-electron closed shell, in the limit Z→N, was proposed on the basis of an investigation of the asymptotic behavior of the corresponding quantum defect: If the outermost atomic orbital is of type nℓ, then in the limit specified above it approaches an (infinitely diffuse) hydrogenic orbital of the form (n-nℓ)ℓ, where nℓ is the number of occupied subshells with angular momentum quantum number ℓ. The consequences of this conjecture concerning the corresponding asymptotic behavior of dipole and quadrupole oscillator strengths are formulated and explored. Reasonably convincing agreement is established for several transitions in the isoelectronic sequences of He, the alkali atoms, B, Al and Cu. Some apparent violations of the presently proposed asymptotic values of the oscillator strengths are pointed out." @default.
- W2982018169 created "2019-11-01" @default.
- W2982018169 creator A5089719253 @default.
- W2982018169 date "2020-01-01" @default.
- W2982018169 modified "2023-10-18" @default.
- W2982018169 title "Asymptotic oscillator strength at the critical charge" @default.
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- W2982018169 doi "https://doi.org/10.1016/j.cplett.2019.136897" @default.
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