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- W2982128409 abstract "Abstract In situ oxidation of the Ga I compound NacNacGa by either N 2 O or pyridine oxide results in the generation of a labile monomeric oxide, NacNacGa(O), which can easily cleave the C−H bonds of aliphatic and aromatic substrates featuring good donor sites. The products of this reaction are gallium organyl hydroxides. DFT calculations show that these reactions start with the formation of NacNac‐Ga(O)(L) adducts, the oxo ligand of which can easily abstract protons from nearby C−H bonds, even for sp 2 ‐hybridized carbon centers. Aliphatic amines do not enter this reaction for kinetic reasons, presumably because of the unfavorable sterics." @default.
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- W2982128409 date "2019-11-14" @default.
- W2982128409 modified "2023-10-15" @default.
- W2982128409 title "Sequential Oxidation and C−H Bond Activation at a Gallium(I) Center" @default.
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- W2982128409 doi "https://doi.org/10.1002/anie.201913028" @default.
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