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- W2982329942 abstract "The reactivity and properties of polyoxometalates (POMs) vary remarkably as a function of the kind of addenda atoms, so the design and synthesis of new mixed-addenda POMs is a promising approach for the further development of the POM-related areas. In the present work, the first Mo/Ta/W ternary mixed-addenda POM (NH4)41H7[K3(H2O)3(P2W15Ta3O62)6(Mo2O4CH3CO2)3(MoO3)2]·85H2O (1), which is composed of 6 {P2W15Ta3O62} linked by 3 {MoV2O4(OOCCH3)+} and 2 {MoVIO3} via 18 novel Mo–O–Ta bridges has been synthesized. The precursor {P2W15Ta3}, which has lower redox potential, is crucial for the formation of 1. The red-brown solid sample of 1 shows strong absorption in the visible region. The visible-light responsive charge transfer from benzylamine to 1 was observed experimentally. 1 was proved to be an efficient photocatalyst under simulated sunlight (AM 1.5G) radiation for the oxidative coupling of primary amines to imines using atmospheric O2." @default.
- W2982329942 created "2019-11-08" @default.
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- W2982329942 date "2019-10-28" @default.
- W2982329942 modified "2023-10-16" @default.
- W2982329942 title "A Giant Mo/Ta/W Ternary Mixed-Addenda Polyoxometalate with Efficient Photocatalytic Activity for Primary Amine Coupling" @default.
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- W2982329942 doi "https://doi.org/10.1021/acsami.9b16694" @default.
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