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- W2982575452 abstract "Abstract Many terpenes may autoxidize under certain conditions to form terpene hydroperoxides, which have been reported to be skin sensitizers that may cause allergic contact dermatitis. The fragrance industry is currently required to monitor terpene hydroperoxide levels in many raw materials by iodometric titration (aka; the peroxide value, or POV test), and to reject lots that exceed a specification limit. We have found that compounds containing the 2‐oxoacid moiety (the “pyruvic acid” moiety) react readily with organic hydroperoxides via an oxidative decarboxylation mechanism. The reaction products include an alcohol corresponding to the reduced hydroperoxide, carbon dioxide, and a carboxylic acid that is one carbon shorter than the starting 2‐oxoacid. Because the hydroperoxide is irreversibly consumed by this reaction, the POV of a 2‐oxoacid‐treated sample is effectively lowered. It follows that the skin sensitizing potential of the treated sample should also be lowered as a result of the hydroperoxide removal." @default.
- W2982575452 created "2019-11-08" @default.
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- W2982575452 date "2019-10-28" @default.
- W2982575452 modified "2023-10-14" @default.
- W2982575452 title "Oxidative decarboxylation of 2‐oxoacids by hydroperoxides can be used to lower peroxide values in citrus oils" @default.
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- W2982575452 doi "https://doi.org/10.1002/ffj.3543" @default.
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