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• W2983206131 abstract "Owing to their low cost and abundant reserves relative to conventional lithium-ion batteries (LIBs), potassium-ion batteries (PIBs), and aluminum-ion batteries (AIBs) have shown appealing potential for electrochemical energy storage, but progress so far has been limited by the lack of suitable electrode materials. In this work, we demonstrated a facile strategy to achieve highly reversible potassium and aluminum ions storage in strongly coupled nanosized MoSe2@carbon matrix, induced through an ion complexation strategy. We present a broad range of electrochemical characterization of the synthesized product that exhibits high specific capacities, good rate capability, and excellent cycling stability toward PIBs and AIBs. Through a series of systematic ex situ X-ray photoelectron spectroscopy (XPS) characterizations and density functional theory (DFT) calculations, the Al3+ intercalation mechanism of MoSe2-based AIBs are elucidated. Moreover, both the assembled PIBs and AIBs worked well when exposed to low and high temperatures within the range of -10 to 50 °C, showing promise for energy storage devices in harsh environment. The present study provides new insights into the exploration of MoSe2 as high-performance electrode materials for PIBs and AIBs." @default.
• W2983206131 created "2019-11-22" @default.
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• W2983206131 date "2019-11-06" @default.
• W2983206131 modified "2023-10-05" @default.
• W2983206131 title "Nanosized MoSe₂@Carbon Matrix: A Stable Host Material for the Highly Reversible Storage of Potassium and Aluminum Ions" @default.
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• W2983206131 doi "https://doi.org/10.1021/acsami.9b16155" @default.
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