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- W2983342871 abstract "A method for the generation of free radicals from thiazolinium salts upon photocatalytic reduction is described. The thiazolinium salts are generated by treatment with methyl triflate of 2-mercaptothiazolines, which can be readily obtained from alkyl bromides and tosylates via a nucleophilic substitution reaction or by hydrothiolation of alkenes. Silyl enol ethers were used to trap the radicals, furnishing ketones after successive single-electron oxidation and elimination of the silyl cation." @default.
- W2983342871 created "2019-11-22" @default.
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- W2983342871 date "2019-11-06" @default.
- W2983342871 modified "2023-10-12" @default.
- W2983342871 title "Photoredox Reaction of 2-Mercaptothiazolinium Salts with Silyl Enol Ethers" @default.
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- W2983342871 doi "https://doi.org/10.1021/acs.joc.9b02478" @default.
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