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- W2983373670 abstract "Cis- and trans-propylcyclohexylamine were identified as primary reaction intermediates of the aliphatic C−N bond cleavage in the hydrodenitrogenation (HDN) network of decahydroquinoline (DHQ). The kinetic parameters of the HDN network were calculated assuming a Langmuir−Hinshelwood mechanism. Three kinds of catalytic sites could be distinguished: aliphatic C(sp3)−N bond cleavage, (de)hydrogenation of a (aromatic) heterocyclic ring, and alkene hydrogenation. The adsorption constants over NiMo/Al2O3 and NiMoP/Al2O3 catalysts were the same for the C(sp3)−N bond cleavage site, while different for the hydrogenation sites. The decreased rate constant of the first C(sp3)−N bond cleavage accounts for the negative effect of phosphorus in the HDN of DHQ. Introduction of Ni to a Mo(P)/Al2O3 catalyst increased the rate constant of the C(sp3)−N bond cleavage by a factor of 2, and that of alkene hydrogenation by a factor of 6." @default.
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- W2983373670 date "1998-01-27" @default.
- W2983373670 modified "2023-10-18" @default.
- W2983373670 title "Kinetics of the Hydrodenitrogenation of Decahydroquinoline over NiMo(P)/Al<sub>2</sub>O<sub>3</sub> Catalysts" @default.
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- W2983373670 doi "https://doi.org/10.1021/ie9703292" @default.
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