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- W2983420512 abstract "A high-valent diiron-oxo species that can react with perfluoroarenes through an oxidative pathway is described. As far as the authors are aware, no enzymatic iron enzymes are able to complete this feat. Furthermore, it is shown that the aromatic hydroxylation of perfluoroarenes involves the activation of strong C−F bonds and operates through a different mechanism than that of arenes. The authors demonstrated a mechanism of defluorination via a ketone intermediate, which is a side-product for aromatic hydroxylation. More information can be found in the Full Paper by A. B. Sorokin, S. P. de Visser, et al. on page 14320." @default.
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- W2983420512 date "2019-09-30" @default.
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- W2983420512 title "Cover Feature: Mechanism of Oxidative Activation of Fluorinated Aromatic Compounds by N‐Bridged Diiron‐Phthalocyanine: What Determines the Reactivity? (Chem. Eur. J. 63/2019)" @default.
- W2983420512 doi "https://doi.org/10.1002/chem.201904315" @default.
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