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• W2984067579 abstract "Reactions of laser-ablated Fe, Ru, and Pt atoms with acetonitrile have been carried out in excess argon, and the products identified in the matrix spectra. CH3CN→Fe and Fe-η2-(NC)–CH3 observed in the original deposition spectra converted to CH3–FeNC on uv irradiation. CH3CN→Ru, the only product detected in the Ru system, dissociated on uv irradiation, but was partly reproduced on subsequent visible irradiation and annealing. Similar behavior was found for CH3CN→Pt. The major products (CH3–FeNC, CH3CN→Ru, and CH3CN→Pt) are the most stable constituents in the previously proposed reaction path for Group 4, 5, 6, and 7 metal atoms and acetonitrile, parallel with the previous results. The Group 8 metal π-coordination products are weakly bound complexes due to limited back-donation to the π*-orbitals of CH3CN. Calculations show that the Fe insertion product has a much less bent structure than the Ru analogue, in line with its higher s-character from the first row transition-metal to the C–Fe bond, and the group 8 metal methylidenes are not agostically distorted. The Pt to N bond in CH3CN→Pt is the strongest of all the metals we have investigated owing in large part to its higher electron affinity, which prevents nitrogen lone pair density from entering the pi* orbitals of the C–N group." @default.
• W2984067579 created "2019-11-22" @default.
• W2984067579 creator A5029634322 @default.
• W2984067579 creator A5036641250 @default.
• W2984067579 date "2019-11-11" @default.
• W2984067579 modified "2023-09-24" @default.
• W2984067579 title "Infrared Spectra of CH₃CN→M, M−η²-(NC)–CH₃, CH₃–MNC Prepared by Reactions of Laser-Ablated Fe, Ru, and Pt Atoms with Acetonitrile in Excess Argon" @default.
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• W2984067579 doi "https://doi.org/10.1021/acs.inorgchem.9b02716" @default.
• W2984067579 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31710217" @default.
• W2984067579 hasPublicationYear "2019" @default.
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