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- W2984164025 abstract "Clay (kaolin, mont-K10 and mont-KSF) supported InCl3, GaCl3, FeCl3 and ZnCl2 catalysts (metal chloride loading=1.1 mmol g−1) show high selectivity (⩾98%) at high conversion in the esterification of tert-butanol by acetic anhydride to tert-butyl acetate (t-BA) and very low activity for the dehydration of tert-butanol at ⩽50°C. For all the catalysts, mont-K10 is the best support and the order of their esterification activity (at 26°C) is: InCl3/mont-K10 (TOF=0.025 s−1) > GaCl3/mont-K10 (0.023 s−1) > FeCl3/mont-K10 (0.02 s−1) ⩾ ZnCl2/mont-K10 (0.019 s−1). InCl3/mont-K10 is highly active, selective and reusable catalyst for the esterification." @default.
- W2984164025 created "2019-11-22" @default.
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- W2984164025 date "2001-05-01" @default.
- W2984164025 modified "2023-10-16" @default.
- W2984164025 title "Selective esterification of tert-butanol by acetic acid anhydride over clay supported InCl3, GaCl3, FeCl3 and InCl2 catalysts" @default.
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- W2984164025 doi "https://doi.org/10.1016/s1566-7367(01)00010-3" @default.
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