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- W2984182470 abstract "Abstract Rare‐earth (RE) doped zinc oxides (ZnO) are regarded as promising materials for application in versatile color‐tuned devices. However, the understanding of underlying luminescence mechanism and the rule of 4 f ‐related electronic transition is still limited, which is full of significance for the exploration of advanced RE‐based ZnO phosphors. Thus, a series of ZnO : RE (RE=Ce, Pr, Nd, Sm, Gd, Tb, Dy, Ho, Er, Tm, Yb) phosphors have been investigated by means of first‐principles calculations. Meanwhile, we also consider the effect of native defects (V O , V Zn ) on the luminescence of ZnO : RE phosphors. Accordingly, four types of electric‐dipole allowed transition processes are figured out in ZnO : RE family. Additionally, we manifest that the V O can further improve the luminescent performance of ZnO : RE phosphors, and give insightful guidance to design desired RE‐based ZnO materials with excellent luminescence." @default.
- W2984182470 created "2019-11-22" @default.
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- W2984182470 date "2019-12-16" @default.
- W2984182470 modified "2023-10-16" @default.
- W2984182470 title "Investigation of 4 <i>f</i> ‐Related Electronic Transitions of Rare‐Earth Doped ZnO Luminescent Materials: Insights from First‐Principles Calculations" @default.
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- W2984182470 doi "https://doi.org/10.1002/cphc.201900981" @default.
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