FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2984421851> ?p ?o ?g. }

• W2984421851 abstract "The absorption and fluorescence emission spectra of a newly synthesized laser grade coumarin dye, 1-((4-methoxyphenoxy) methyl)-3H-benzo[f]chromen-3-one (4-MPMBC), have been recorded in various solvents having different polarities. The spectrum peak was found to shift toward a higher wavelength with an increase in the solvent polarity. The dipole moments of the ground state (μ g ) and excited state (μ e ) were estimated using the Lippert, Bakshiev, and Kawski–Chamma–Viallet equations. The μ e values were found to be greater than the μ g values in all solvents, indicating that the dye is more polar in the excited state than in the ground state. The absorption maximum and emission maximum energies, ground- and excited-state dipole moments, and HOMO–LUMO energy gaps were estimated using Gaussian 16W. These have been compared with the experimental results. The estimated chemical hardness of the dye molecule indicates the soft nature in all of the solvents. The reactive centers such as nucleophilic and electrophilic sites were identified along with contour action using electrostatic potential three-dimensional map density functional theory analysis. The fluorescence quenching has been studied in solvents of varying polarities using aniline as a quencher. The quenching process was found to follow the Stern–Volmer equation and was studied by considering the role of diffusion. In all solvents, the probability of quenching per encounter (p) was found to be less than unity. The activation energy for diffusion and activation energy for quenching were estimated using the values of p." @default.
• W2984421851 created "2019-11-22" @default.
• W2984421851 creator A5021072828 @default.
• W2984421851 creator A5033755510 @default.
• W2984421851 creator A5035654374 @default.
• W2984421851 creator A5081418045 @default.
• W2984421851 date "2020-08-01" @default.
• W2984421851 modified "2023-09-24" @default.
• W2984421851 title "Dipole moments and quenching of fluorescence of a new coumarin dye" @default.
• W2984421851 cites W1971430405 @default.
• W2984421851 cites W1978011301 @default.
• W2984421851 cites W1979370423 @default.
• W2984421851 cites W1988535541 @default.
• W2984421851 cites W1993327079 @default.
• W2984421851 cites W1995970197 @default.
• W2984421851 cites W2000215402 @default.
• W2984421851 cites W2002279998 @default.
• W2984421851 cites W2009180389 @default.
• W2984421851 cites W2020027697 @default.
• W2984421851 cites W2020438884 @default.
• W2984421851 cites W2029609435 @default.
• W2984421851 cites W2030974307 @default.
• W2984421851 cites W2044141002 @default.
• W2984421851 cites W2045039436 @default.
• W2984421851 cites W2045989617 @default.
• W2984421851 cites W2049139446 @default.
• W2984421851 cites W2069723612 @default.
• W2984421851 cites W2072188078 @default.
• W2984421851 cites W2076777135 @default.
• W2984421851 cites W2081389014 @default.
• W2984421851 cites W2090391132 @default.
• W2984421851 cites W2094607513 @default.
• W2984421851 cites W2114793608 @default.
• W2984421851 cites W2147422985 @default.
• W2984421851 cites W2155782337 @default.
• W2984421851 cites W2528162033 @default.
• W2984421851 cites W2809166585 @default.
• W2984421851 cites W2906998809 @default.
• W2984421851 cites W2910914593 @default.
• W2984421851 cites W2963405861 @default.
• W2984421851 cites W2971092120 @default.
• W2984421851 doi "https://doi.org/10.1139/cjp-2019-0517" @default.
• W2984421851 hasPublicationYear "2020" @default.
• W2984421851 type Work @default.
• W2984421851 sameAs 2984421851 @default.
• W2984421851 citedByCount "0" @default.
• W2984421851 crossrefType "journal-article" @default.
• W2984421851 hasAuthorship W2984421851A5021072828 @default.
• W2984421851 hasAuthorship W2984421851A5033755510 @default.
• W2984421851 hasAuthorship W2984421851A5035654374 @default.
• W2984421851 hasAuthorship W2984421851A5081418045 @default.
• W2984421851 hasConcept C113196181 @default.
• W2984421851 hasConcept C119824511 @default.
• W2984421851 hasConcept C120665830 @default.
• W2984421851 hasConcept C121332964 @default.
• W2984421851 hasConcept C121745418 @default.
• W2984421851 hasConcept C125287762 @default.
• W2984421851 hasConcept C1276947 @default.
• W2984421851 hasConcept C173523689 @default.
• W2984421851 hasConcept C178790620 @default.
• W2984421851 hasConcept C181500209 @default.
• W2984421851 hasConcept C184779094 @default.
• W2984421851 hasConcept C185592680 @default.
• W2984421851 hasConcept C4839761 @default.
• W2984421851 hasConcept C67218372 @default.
• W2984421851 hasConcept C69523127 @default.
• W2984421851 hasConcept C75473681 @default.
• W2984421851 hasConcept C91881484 @default.
• W2984421851 hasConcept C96141758 @default.
• W2984421851 hasConceptScore W2984421851C113196181 @default.
• W2984421851 hasConceptScore W2984421851C119824511 @default.
• W2984421851 hasConceptScore W2984421851C120665830 @default.
• W2984421851 hasConceptScore W2984421851C121332964 @default.
• W2984421851 hasConceptScore W2984421851C121745418 @default.
• W2984421851 hasConceptScore W2984421851C125287762 @default.
• W2984421851 hasConceptScore W2984421851C1276947 @default.
• W2984421851 hasConceptScore W2984421851C173523689 @default.
• W2984421851 hasConceptScore W2984421851C178790620 @default.
• W2984421851 hasConceptScore W2984421851C181500209 @default.
• W2984421851 hasConceptScore W2984421851C184779094 @default.
• W2984421851 hasConceptScore W2984421851C185592680 @default.
• W2984421851 hasConceptScore W2984421851C4839761 @default.
• W2984421851 hasConceptScore W2984421851C67218372 @default.
• W2984421851 hasConceptScore W2984421851C69523127 @default.
• W2984421851 hasConceptScore W2984421851C75473681 @default.
• W2984421851 hasConceptScore W2984421851C91881484 @default.
• W2984421851 hasConceptScore W2984421851C96141758 @default.
• W2984421851 hasLocation W29844218511 @default.
• W2984421851 hasOpenAccess W2984421851 @default.
• W2984421851 hasPrimaryLocation W29844218511 @default.
• W2984421851 hasRelatedWork W15145026 @default.
• W2984421851 hasRelatedWork W16047476 @default.
• W2984421851 hasRelatedWork W17770871 @default.
• W2984421851 hasRelatedWork W25224203 @default.
• W2984421851 hasRelatedWork W26829069 @default.
• W2984421851 hasRelatedWork W31783059 @default.
• W2984421851 hasRelatedWork W42564129 @default.
• W2984421851 hasRelatedWork W43929398 @default.
• W2984421851 hasRelatedWork W4518550 @default.
• W2984421851 hasRelatedWork W988316 @default.

• next