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• W2985247534 abstract "B-Phenyl BIII subporphyrin-α-diones prepared in a three-step reaction sequence from the parent subporphyrin were condensed with 1,2-diaminobenzenes to give the corresponding quinoxaline-fused subporphyrins in variable yields. Quinoxaline-fused B-phenyl-5,10,15-triphenyl BIII subporphyrin was transformed to the corresponding subporphyrin-α-dione in the same three-step reaction sequence, which was then condensed with 1,2-diaminobenzene to give doubly quinoxaline-fused subporphyrin. These quinoxaline-fused subporphyrins exhibit redshifted absorption and fluorescence spectra compared with the parent one. A singly quinoxaline-fused subporphyrin bearing three meso-bis(4-dimethylaminophenyl)aminophenyl substituents shows blueshifted fluorescence in less polar solvent, which has been ascribed to emission associated with charge recombination of intramolecular charge transfer (CT) state." @default.
• W2985247534 created "2019-11-22" @default.
• W2985247534 creator A5004168945 @default.
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• W2985247534 date "2019-11-06" @default.
• W2985247534 modified "2023-09-27" @default.
• W2985247534 title "Singly and Doubly Quinoxaline‐Fused B ^III Subporphyrins" @default.
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• W2985247534 doi "https://doi.org/10.1002/chem.201904151" @default.
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