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- W2985484962 abstract "Local electric fields were calculated in the region of the conduction layer occupied by water molecules in hydrated b-alumina, and the dipole derivatives for the H/sub 2/O normal vibrations in Li and Na/sub 0.3/Li/sub 0.7/ ..beta..-alumina were determined from the local-field-corrected absorption intensities. The local field has a significant effect on the relative magnitudes of ..nu../sub 1/ and ..nu../sub 3/. However, a calculation of the polar tensors of H/sub 2/O and Li ..beta..-alumina shows that the large intensity of ..nu../sub 1/ compared to the gas phase value is due to hydrogen bonding which results in a large increase in the component of the dipole moment change along the O--H bond with displacement of the proton." @default.
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- W2985484962 date "1984-01-01" @default.
- W2985484962 modified "2023-09-23" @default.
- W2985484962 title "Local fields and infrared absorption intensities of H/sub 2/O in hydrated. beta. -alumina" @default.
- W2985484962 hasPublicationYear "1984" @default.
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