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• W2985789168 abstract "The first phosphine-stabilized cationic rhodium silylene complex is reported. A dihydrido-silylene-Rh(iii) compound reacts with water and alcohols forming alkoxysilyl-Rh(iii) complexes and hydrogen gas. Moreover, benzophenone reacts with a cationic silylene rhodium complex leading to the reduction of the carbonyl group and the formation of an alkoxysilyl-Rh(iii) compound which has been identified as a likely intermediate in the mechanism for the hydrosilylation of ketones proposed by Hofmann and Gade." @default.
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• W2985789168 date "2019-01-01" @default.
• W2985789168 modified "2023-09-27" @default.
• W2985789168 title "A phosphine-stabilized silylene rhodium complex" @default.
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• W2985789168 doi "https://doi.org/10.1039/c9dt04071d" @default.
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