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- W2986011796 abstract "The shortage of fossil resources and strict environmental regulations have ignited great efforts in the production of bio-based fuels and chemicals via biorefinery. Herein, considering the strong interaction between Ni and Mg species, we specially designed and prepared Ni/CaMgO and Ni/MgSiO for alkylation and hydrodeoxygenation (HDO) reactions during the upgrading of the acetone–butanol–ethanol (ABE) fermentation mixture. Gratifyingly, the Mg-decorated catalysts exhibited great catalytic performance: a selectivity of 63.9% under a conversion of 94.2% was achieved for C8–C15 ketones and alcohols, which is higher than that over other heterogeneous alkali-based catalysts, and the obtained mixture was completely converted into the corresponding alkanes at 190 °C (H2 pressure: 1 MPa). It is worth noting that jet fuels or gasoline could be efficiently and selectively obtained by facile adjustment of the composition of the ABE fermentation product. Moreover, investigation on the structure–activity correlation confirmed that the outstanding activity of Ni/MgSiO for HDO could be attributed to the synergic catalysis between Ni0 and strong acid sites. The Ni/CaMgO and Ni/MgSiO catalysts reported in this work offer three advantages: selectively upgrading zymotic biomass wastes into biofuels, replacing the expensive noble metal (Pd) by the base metal (Ni), and realizing the HDO process under mild conditions and complying with the principles of “green chemistry”. Overall, this work opens a new possibility for biofuel production, which is conductive to the rational design and implementation of highly active heterogeneous catalysts." @default.
- W2986011796 created "2019-11-22" @default.
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- W2986011796 date "2019-11-11" @default.
- W2986011796 modified "2023-10-15" @default.
- W2986011796 title "Domino Reactions for Biofuel Production from Zymotic Biomass Wastes over Bifunctional Mg-Containing Catalysts" @default.
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- W2986011796 doi "https://doi.org/10.1021/acssuschemeng.9b04311" @default.
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