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• W2986015038 abstract "Here, an enantioselective aza-Reformatsky reaction using acyclic ketimine substrates is presented. Using α-phosphorated ketimines as electrophilic substrates and a simple BINOL-derived ligand, phosphorated analogues of aspartic acid holding chiral tetrasubstituted carbons are efficiently obtained with excellent enantioselectivity through an asymmetric organocatalytic Reformatsky-type reaction. The phosphorated analogues of aspartic acid have been used for the synthesis of phosphorus-containing enantiopure tetrasubstituted β-lactams." @default.
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• W2986015038 date "2019-11-15" @default.
• W2986015038 modified "2023-10-10" @default.
• W2986015038 title "Enantioselective Aza-Reformatsky Reaction with Ketimines" @default.
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• W2986015038 doi "https://doi.org/10.1021/acs.orglett.9b03669" @default.
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