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• W2986114045 endingPage "121042" @default.
• W2986114045 startingPage "121042" @default.
• W2986114045 abstract "Our systematic exploration of chainlike borate in the hybrid templated borate systems has led to three new borates, namely, [GaTETA]·[B5O8(OH)2]·H2O, [InTETA]·[B5O8(OH)2]·1.5H2O, and [Cd(1,2-dap)]·[B6O11(OH)2]·H2O. The structures of the three borates were determined by single-crystal X-ray diffraction. [Cd(1,2-dap)]·[B6O11(OH)2]·H2O represents the first example of chainlike borate containing Cd2+ transition metal cations and [B6O11(OH)2] cluster. [GaTETA]·[B5O8(OH)2]·H2O is isostructural with [InTETA]·[B5O8(OH)2]·1.5H2O, whose structure features a one-dimensional (1D) polyatomic chain constructed of MO2N4 octahedron and [B5O8(OH)2] groups, such chains are further bridged by HBs resulting in a three-dimensional (3D) supermolecular network. Optical and luminescent property measurements have also been performed on the three compounds. Only fluorescence intensity of [GaTETA]·[B5O8(OH)2]·H2O decreased fiercely with temperature increase. Besides, the band gap of [GaTETA]·[B5O8(OH)2]·H2O and its isomer [InTETA]·[B5O8(OH)2]·1.5H2O and [Cd(1,2-dap)]·[B6O11(OH)2]·H2O are very distinct from each other, it may indicate that optical and luminescent property of hybrid borate can be manipulated by adjusting of polyatomic cluster and metallic ion." @default.
• W2986114045 created "2019-11-22" @default.
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• W2986114045 date "2020-01-01" @default.
• W2986114045 modified "2023-09-25" @default.
• W2986114045 title "The tunable luminescent property and wide band gap in three 1D hybrid templated borates containing different metallic ions and oxoboron clusters" @default.
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• W2986114045 doi "https://doi.org/10.1016/j.jssc.2019.121042" @default.
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