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- W2986941094 abstract "Abstract We present the crystal growth as well as the structural, chemical and physical chracterization of SmRh 2 Si 2 single crystals. Their ground state is antiferromagnetic, as indicated by the behaviour of the magnetic susceptibility and the specific heat at the second order phase transition observed at T N = 64 K. The Sommerfeld coefficient is small and similar to that of LuRh 2 Si 2 with <?CDATA ${gamma }_{0}approx 7$?> <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML overflow=scroll> <mml:msub> <mml:mrow> <mml:mi>γ</mml:mi> </mml:mrow> <mml:mrow> <mml:mn>0</mml:mn> </mml:mrow> </mml:msub> <mml:mo>≈</mml:mo> <mml:mn>7</mml:mn> </mml:math> mJ/(molK 2 ). Susceptibility measurements show no Curie-Weiss behaviour at high temperatures which is a consequence of the large Van-Vleck contribution of the excited multiplets of Sm 3+ . Previous angle-resolved photoemission studies showed that at 10 K, the valence of the Sm ions is smaller than three at the surface as well as in the bulk, suggesting a possible Kondo screening of the Sm 3+ ions. This could not be observed in our thermodynamic and transport measurements." @default.
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- W2986941094 date "2019-11-27" @default.
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- W2986941094 title "Bulk properties of single crystals of the valence-unstable compound SmRh<sub>2</sub>Si<sub>2</sub>" @default.
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- W2986941094 doi "https://doi.org/10.1088/2053-1591/ab5814" @default.
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