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- W2987013375 abstract "Herein, we describe a rapid microwave‐assisted, metal‐free synthesis of substituted quinoxalinones and quinoxalines using the carbene‐mediated reaction between aryldiazo esters and 1,2‐diamines. The reaction can encompass a range of substituents and structural variations to afford quinoxalin‐2‐ones in 14–80 % yield and corresponding quinoxalines in good to excellent yields upon oxidation (67–96 %). The approach can be employed to generate symmetrical and unsymmetrical 2,3‐diarylquinoxalines, bis‐quinoxalines as well as novel quinoxaline‐substituted diazo esters and should be a valuable addition to the heterocycle synthesis toolbox." @default.
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- W2987013375 date "2020-11-17" @default.
- W2987013375 modified "2023-09-29" @default.
- W2987013375 title "Microwave‐Assisted Synthesis of Heterocycles from Aryldiazoacetates**" @default.
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- W2987013375 doi "https://doi.org/10.1002/ejoc.202001155" @default.
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