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• W2987121344 startingPage "1024" @default.
• W2987121344 abstract "Structural features and kinetics of the transition between ordered metastable b.c.c.-derived D0 3 and equilibrium f.c.c.-derived L1 2 phases of Fe– x Ga alloys ( x = 27.2% and 28.0%) have been analyzed by in situ real-time neutron diffraction during isothermal annealing in the temperature range 405–470°C. It has been revealed that the transition proceeds with alternation of the first- and second-order phase transformations according to a D0 3 → A2 → A1 → L1 2 scheme, where A2 and A1 are disordered b.c.c. and f.c.c. structures. Deformations of the crystal lattice that arise due to these transitions are determined. The kinetics of the L1 2 phase nucleation and growth were analyzed in the frame of the Johnson–Mehl–Avrami–Kolmogorov (JMAK) model; however, only the early stage of the D0 3 → L1 2 transition is well described by the JMAK equation. The value of the Avrami exponent corresponds to the constant growth rate of the new L1 2 phase and decreasing nucleation rate in the Fe–27.2Ga alloy and indicates the presence of pre-existing nucleation centres of the L1 2 phase in the Fe–28.0Ga alloy." @default.
• W2987121344 created "2019-11-22" @default.
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• W2987121344 date "2019-11-09" @default.
• W2987121344 modified "2023-09-23" @default.
• W2987121344 title "The first- and second-order isothermal phase transitions in Fe₃Ga-type compounds" @default.
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• W2987121344 doi "https://doi.org/10.1107/s2052520619013106" @default.
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• W2987121344 hasPublicationYear "2019" @default.
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