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- W2987134054 abstract "Abstract For separation of enantiomers in presence of a chiral selector, data obtained with the 1D dynamic simulators SIMUL5complex and GENTRANS are compared to data predicted by PeakMaster 6, a recently released generalized model of the linear theory of electromigration. Four electrophoretic systems with stereoisomers of weak bases were investigated. They deal with the estimation of input data for complexation together with the elucidation of the origin of observed system peaks, the interference of analyte and system peak migration, the change of enantiomer migration order as function of the selector concentration and the inversion of analyte migration direction in presence of a multiply negatively charged selector. For all systems, data predicted with PeakMaster 6 are in agreement with those of the dynamic simulators and simulation data compare well with experimental data that were monitored with setups featuring conductivity and/or UV absorbance detection along the capillary. SIMUL5complex and GENTRANS provide the full dynamics of any buffer and sample arrangement and require very long execution time intervals. PeakMaster 6 is restricted to conventional CZE, is based on an approximate solution of the transport equations, provides data for realistic experimental conditions within seconds and represents a practical tool for an experimentalist." @default.
- W2987134054 created "2019-11-22" @default.
- W2987134054 creator A5013013472 @default.
- W2987134054 creator A5053912018 @default.
- W2987134054 date "2019-11-18" @default.
- W2987134054 modified "2023-09-27" @default.
- W2987134054 title "Contemporary chiral simulators for capillary zone electrophoresis" @default.
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- W2987134054 doi "https://doi.org/10.1002/elps.201900363" @default.
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