FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2987686687> ?p ?o ?g. }

• W2987686687 endingPage "125349" @default.
• W2987686687 startingPage "125349" @default.
• W2987686687 abstract "This study investigates electrooxidation of short (C3-C6) and long (C7-C-18) chain perfluorocarboxylic acids (PFCAs) including perfluorooctane sulfonate (PFOA) using Si/BDD electrode. The effect of operational parameters (supporting electrolyte type, applied current density, and initial pH) were explored for PFOA removal. At the optimized conditions, 74% TOC removal and 37% defluorination ratio were gained for 10 mg L-1 of PFOA solution which evidences that the shorter chain PFCAs were formed. The PFOA degradation pathway followed one direct electron transfer from PFOA molecule to anode surface. Then two different degradation pathways were proposed. The first proposed degradation mechanism involved the reaction of perfluoroheptyl radical and hydroxyl radical, the release of HF and hydrolysis. The second mechanism involved the reaction between perfluoroheptyl radical and O2, formation of C7F15O and perfluorohexyl radical with releasing COF2. The removal of short- (C3-C6) and long-chain PFCAs (C7-C18) was also characterized. More than 95% of removal efficiency was gained for all long-chain PFCAs, excluding C7. The removal ratios of short-chain PFCAs (C3-C6) were 39%, 41%, 66% and 70% for C3, C4, C5 and C6, respectively. Contrary to long-chain PFCAs, chain-length dependence for short-chain PFCAs were observed. Defluorination ratio of short-chain PFCAs was only 45% signifying that defluorination partially occurred. Water matrix did not significantly affect the degradation of short-chain PFCAs in deionized water (DI), river water and secondary effluent of a wastewater treatment plant (WWTP). In contrast, defluorination ratio of long-chain PFCAs was noticeably affected by water matrix with the order of DI water > WWTP effluent > river water." @default.
• W2987686687 created "2019-11-22" @default.
• W2987686687 creator A5046178647 @default.
• W2987686687 creator A5063526077 @default.
• W2987686687 date "2020-03-01" @default.
• W2987686687 modified "2023-10-14" @default.
• W2987686687 title "Electrooxidation of short and long chain perfluorocarboxylic acids using boron doped diamond electrodes" @default.
• W2987686687 cites W1477096711 @default.
• W2987686687 cites W1747894519 @default.
• W2987686687 cites W1926950498 @default.
• W2987686687 cites W1973399010 @default.
• W2987686687 cites W1980448791 @default.
• W2987686687 cites W1982293068 @default.
• W2987686687 cites W1990113330 @default.
• W2987686687 cites W1990257642 @default.
• W2987686687 cites W1993261286 @default.
• W2987686687 cites W1994212218 @default.
• W2987686687 cites W2001700734 @default.
• W2987686687 cites W2032766019 @default.
• W2987686687 cites W2037991945 @default.
• W2987686687 cites W2039816772 @default.
• W2987686687 cites W2041269463 @default.
• W2987686687 cites W2042891502 @default.
• W2987686687 cites W2046299132 @default.
• W2987686687 cites W2048546446 @default.
• W2987686687 cites W2056547176 @default.
• W2987686687 cites W2060648283 @default.
• W2987686687 cites W2066736542 @default.
• W2987686687 cites W2075672910 @default.
• W2987686687 cites W2081974921 @default.
• W2987686687 cites W2087233783 @default.
• W2987686687 cites W2093067659 @default.
• W2987686687 cites W2095173462 @default.
• W2987686687 cites W2099008184 @default.
• W2987686687 cites W2137375601 @default.
• W2987686687 cites W2156040892 @default.
• W2987686687 cites W2158426593 @default.
• W2987686687 cites W2207549316 @default.
• W2987686687 cites W2217587892 @default.
• W2987686687 cites W2277696037 @default.
• W2987686687 cites W2290180541 @default.
• W2987686687 cites W2322905289 @default.
• W2987686687 cites W2464248487 @default.
• W2987686687 cites W2506232979 @default.
• W2987686687 cites W2580973601 @default.
• W2987686687 cites W2588502327 @default.
• W2987686687 cites W2604422958 @default.
• W2987686687 cites W2616838187 @default.
• W2987686687 cites W2735342889 @default.
• W2987686687 cites W2758695957 @default.
• W2987686687 cites W2769539681 @default.
• W2987686687 cites W2769689563 @default.
• W2987686687 cites W2776422676 @default.
• W2987686687 cites W2784747481 @default.
• W2987686687 cites W2790306665 @default.
• W2987686687 cites W2791059491 @default.
• W2987686687 cites W2793502149 @default.
• W2987686687 cites W2800417997 @default.
• W2987686687 cites W2801190942 @default.
• W2987686687 cites W2804326322 @default.
• W2987686687 cites W2886781857 @default.
• W2987686687 cites W2891857229 @default.
• W2987686687 doi "https://doi.org/10.1016/j.chemosphere.2019.125349" @default.
• W2987686687 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31756655" @default.
• W2987686687 hasPublicationYear "2020" @default.
• W2987686687 type Work @default.
• W2987686687 sameAs 2987686687 @default.
• W2987686687 citedByCount "45" @default.
• W2987686687 countsByYear W29876866872020 @default.
• W2987686687 countsByYear W29876866872021 @default.
• W2987686687 countsByYear W29876866872022 @default.
• W2987686687 countsByYear W29876866872023 @default.
• W2987686687 crossrefType "journal-article" @default.
• W2987686687 hasAuthorship W2987686687A5046178647 @default.
• W2987686687 hasAuthorship W2987686687A5063526077 @default.
• W2987686687 hasBestOaLocation W29876866871 @default.
• W2987686687 hasConcept C107872376 @default.
• W2987686687 hasConcept C127413603 @default.
• W2987686687 hasConcept C147455438 @default.
• W2987686687 hasConcept C147789679 @default.
• W2987686687 hasConcept C17525397 @default.
• W2987686687 hasConcept C17538187 @default.
• W2987686687 hasConcept C178790620 @default.
• W2987686687 hasConcept C185592680 @default.
• W2987686687 hasConcept C2775979320 @default.
• W2987686687 hasConcept C2778894819 @default.
• W2987686687 hasConcept C2779679103 @default.
• W2987686687 hasConcept C2781314072 @default.
• W2987686687 hasConcept C41008148 @default.
• W2987686687 hasConcept C52859227 @default.
• W2987686687 hasConcept C537181965 @default.
• W2987686687 hasConcept C68801617 @default.
• W2987686687 hasConcept C76155785 @default.
• W2987686687 hasConcept C87717796 @default.
• W2987686687 hasConcept C89395315 @default.
• W2987686687 hasConcept C94061648 @default.
• W2987686687 hasConcept C94412978 @default.
• W2987686687 hasConceptScore W2987686687C107872376 @default.

• next