Matches in SemOpenAlex for { <https://semopenalex.org/work/W2987736426> ?p ?o ?g. }
- W2987736426 endingPage "17988" @default.
- W2987736426 startingPage "17983" @default.
- W2987736426 abstract "Selective methylene C-H oxidation for the synthesis of alcohols with a broad scope and functional group tolerance is challenging due to the high proclivity for further oxidation of alcohols to ketones. Here, we report the selective synthesis of benzylic alcohols employing bis(methanesulfonyl) peroxide as an oxidant. We attempt to provide a rationale for the selectivity for monooxygenation, which is distinct from previous work; a proton-coupled electron transfer mechanism (PCET) may account for the difference in reactivity. We envision that our method will be useful for applications in the discovery of drugs and agrochemicals." @default.
- W2987736426 created "2019-11-22" @default.
- W2987736426 creator A5023279776 @default.
- W2987736426 creator A5048840249 @default.
- W2987736426 creator A5081084428 @default.
- W2987736426 date "2019-11-05" @default.
- W2987736426 modified "2023-10-12" @default.
- W2987736426 title "Synthesis of Benzylic Alcohols by C–H Oxidation" @default.
- W2987736426 cites W1956858148 @default.
- W2987736426 cites W1957515359 @default.
- W2987736426 cites W1966061314 @default.
- W2987736426 cites W1974457621 @default.
- W2987736426 cites W1975179420 @default.
- W2987736426 cites W1985769118 @default.
- W2987736426 cites W1986895238 @default.
- W2987736426 cites W1989269725 @default.
- W2987736426 cites W1994069376 @default.
- W2987736426 cites W1997411473 @default.
- W2987736426 cites W2006614340 @default.
- W2987736426 cites W2007708141 @default.
- W2987736426 cites W2012323328 @default.
- W2987736426 cites W2018558595 @default.
- W2987736426 cites W2019406135 @default.
- W2987736426 cites W2041695659 @default.
- W2987736426 cites W2041930594 @default.
- W2987736426 cites W2047186810 @default.
- W2987736426 cites W2056760113 @default.
- W2987736426 cites W2076655264 @default.
- W2987736426 cites W2078899588 @default.
- W2987736426 cites W2091675012 @default.
- W2987736426 cites W2142244352 @default.
- W2987736426 cites W2160790360 @default.
- W2987736426 cites W2183218012 @default.
- W2987736426 cites W2327318545 @default.
- W2987736426 cites W2332310400 @default.
- W2987736426 cites W2333096653 @default.
- W2987736426 cites W2345777662 @default.
- W2987736426 cites W2488628364 @default.
- W2987736426 cites W2530938854 @default.
- W2987736426 cites W2752167198 @default.
- W2987736426 cites W2774942062 @default.
- W2987736426 cites W2792987622 @default.
- W2987736426 cites W2892082086 @default.
- W2987736426 cites W2901043444 @default.
- W2987736426 cites W2903798735 @default.
- W2987736426 cites W2907956604 @default.
- W2987736426 cites W2950610632 @default.
- W2987736426 cites W2951327262 @default.
- W2987736426 cites W2953175234 @default.
- W2987736426 cites W2956043296 @default.
- W2987736426 cites W2962317364 @default.
- W2987736426 cites W2981569022 @default.
- W2987736426 cites W3042874734 @default.
- W2987736426 cites W788427216 @default.
- W2987736426 cites W1971737897 @default.
- W2987736426 doi "https://doi.org/10.1021/jacs.9b09496" @default.
- W2987736426 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/6863597" @default.
- W2987736426 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31689095" @default.
- W2987736426 hasPublicationYear "2019" @default.
- W2987736426 type Work @default.
- W2987736426 sameAs 2987736426 @default.
- W2987736426 citedByCount "65" @default.
- W2987736426 countsByYear W29877364262019 @default.
- W2987736426 countsByYear W29877364262020 @default.
- W2987736426 countsByYear W29877364262021 @default.
- W2987736426 countsByYear W29877364262022 @default.
- W2987736426 countsByYear W29877364262023 @default.
- W2987736426 crossrefType "journal-article" @default.
- W2987736426 hasAuthorship W2987736426A5023279776 @default.
- W2987736426 hasAuthorship W2987736426A5048840249 @default.
- W2987736426 hasAuthorship W2987736426A5081084428 @default.
- W2987736426 hasBestOaLocation W29877364261 @default.
- W2987736426 hasConcept C114157696 @default.
- W2987736426 hasConcept C118792377 @default.
- W2987736426 hasConcept C123669783 @default.
- W2987736426 hasConcept C142724271 @default.
- W2987736426 hasConcept C161790260 @default.
- W2987736426 hasConcept C178790620 @default.
- W2987736426 hasConcept C185592680 @default.
- W2987736426 hasConcept C204787440 @default.
- W2987736426 hasConcept C21951064 @default.
- W2987736426 hasConcept C2776910235 @default.
- W2987736426 hasConcept C2777332933 @default.
- W2987736426 hasConcept C2777454769 @default.
- W2987736426 hasConcept C2781048764 @default.
- W2987736426 hasConcept C521977710 @default.
- W2987736426 hasConcept C71924100 @default.
- W2987736426 hasConcept C75473681 @default.
- W2987736426 hasConceptScore W2987736426C114157696 @default.
- W2987736426 hasConceptScore W2987736426C118792377 @default.
- W2987736426 hasConceptScore W2987736426C123669783 @default.
- W2987736426 hasConceptScore W2987736426C142724271 @default.
- W2987736426 hasConceptScore W2987736426C161790260 @default.
- W2987736426 hasConceptScore W2987736426C178790620 @default.
- W2987736426 hasConceptScore W2987736426C185592680 @default.
- W2987736426 hasConceptScore W2987736426C204787440 @default.
- W2987736426 hasConceptScore W2987736426C21951064 @default.
- W2987736426 hasConceptScore W2987736426C2776910235 @default.