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• W2988016768 abstract "Fluidized catalytic cracking (FCC) converts hydrocarbons in the presence of a catalyst based on faujazite zeolite (USY and REY). While hydrocarbon is poorly reactive, biomass and its derived compounds are highly functionalized and not suitable to a typical FCC process. To overcome this limitation biomass was first converted into a dense and stable bio-crude composed mainly of ketal-sugar derivatives by using acetone in diluted acid. Here, a representative compound of this bio-crude, 1,2:3,5-di-O-isopropylidene-α-D-xylofuranose (DX) in n-hexane, was converted by USY and a commercial FCC catalyst containing USY, at 500°C, in a fixed bed and fluidized bed reactors respectively. Faujasite Y is very efficient in converting DX. More than 95% conversion was observed in all tests. Over 60 wt% was liquid products, followed by gas products and only around 10% or less in coke. The higher the catalyst activity the greater the aromatics in the liquid products and yet higher coke yields were observed. In particular, simulating more practical application conditions: using deactivated catalyst in a fluidized bed reactor, improved green hydrocarbons production (mono-aromatic up to ten carbons and light hydrocarbon up to eight carbons) and unprecedented lower coke yield (≈5 wt.%) for bio-feeds. The present results further suggest that catalyst will play a primary role to convert the bio-crude into target hydrocarbons and overcome the transition of a non-renewable to a renewable refinery feed." @default.
• W2988016768 created "2019-11-22" @default.
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• W2988016768 date "2019-11-01" @default.
• W2988016768 modified "2023-10-18" @default.
• W2988016768 title "Ketal Sugar Conversion Into Green Hydrocarbons by Faujasite Zeolite in a Typical Catalytic Cracking Process" @default.
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• W2988016768 doi "https://doi.org/10.3389/fchem.2019.00720" @default.
• W2988016768 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/6839337" @default.
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